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Zhouyu ZHANG, Hao CHEN, Zhenglin HU, Shoubin ZHOU, Lan ZHANG, Jiayan LUO
《能源前沿(英文)》 2022年 第16卷 第5期 页码 706-733 doi: 10.1007/s11708-022-0833-9
关键词: composite solid electrolytes active filler/framework ion conduction path interphase compatibility multilayer design
Localized high-concentration electrolytes for lithium metal batteries: progress and prospect
《化学科学与工程前沿(英文)》 2023年 第17卷 第10期 页码 1354-1371 doi: 10.1007/s11705-022-2286-4
关键词: high-concentration electrolyte localized high-concentration electrolyte lithium metal battery solid electrolyte interphase dendrite
《能源前沿(英文)》 2023年 第17卷 第1期 页码 43-71 doi: 10.1007/s11708-022-0853-5
关键词: electrolyte lithium-ion low temperature aerospace solid-electrolyte interface
Recent advances toward high voltage, EC-free electrolytes for graphite-based Li-ion battery
Tong Zhang, Elie Paillard
《化学科学与工程前沿(英文)》 2018年 第12卷 第3期 页码 577-591 doi: 10.1007/s11705-018-1758-z
Lithium-ion batteries are a key technology in today’s world and improving their performances requires, in many cases, the use of cathodes operating above the anodic stability of state-of-the-art electrolytes based on ethylene carbonate (EC) mixtures. EC, however, is a crucial component of electrolytes, due to its excellent ability to allow graphite anode operation–also required for high energy density batteries–by stabilizing the electrode/electrolyte interface. In the last years, many alternative electrolytes, aiming at allowing high voltage battery operation, have been proposed. However, often, graphite electrode operation is not well demonstrated in these electrolytes. Thus, we review here the high voltage, EC-free alternative electrolytes, focusing on those allowing the steady operation of graphite anodes. This review covers electrolyte compositions, with the widespread use of additives, the change in main lithium salt, the effect of anion (or Li salt) concentration, but also reports on graphite protection strategies, by coatings or artificial solid electrolyte interphase (SEI) or by use of water-soluble binder for electrode processing as these can also enable the use of graphite in electrolytes with suboptimal intrinsic SEI formation ability.
关键词: lithium-ion electrolyte solid electrolyte interphase additives high voltage graphite
A multiscale material model for heterogeneous liquid droplets in solid soft composites
《结构与土木工程前沿(英文)》 2021年 第15卷 第5期 页码 1292-1299 doi: 10.1007/s11709-021-0771-3
关键词: liquid in solid soft composite computational modeling multiscale model heterogeneity
谢富丞,王诚,毛宗强
《中国工程科学》 2013年 第15卷 第2期 页码 72-76
固体氧化物燃料电池(SOFC)是一种高效、环保的发电装置。低温化是SOFC的主要发展方向。探索适合在低温(400~600 ℃)条件下操作的高性能电解质材料是SOFC低温化发展的关键。近年来,研究人员发展了新型的复合电解质材料,取得了较好的成果。本文综述了近年来低温SOFC复合电解质材料的研究进展,简要介绍了复合电解质材料的特点、类型和传导机理。
钠超离子导体型固体电解质的改性及其在钠离子电池中的应用 Article
张强强, 周权, 陆雅翔, 邵元骏, 戚钰若, 戚兴国, 钟贵明, 杨勇, 陈立泉, 胡勇胜
《工程(英文)》 2022年 第8卷 第1期 页码 170-180 doi: 10.1016/j.eng.2021.04.028
固体电解质的低离子电导率及固体电解质与固态电极之间较差的界面可靠性是阻碍固态钠电池(SSSB)应用的两大紧迫挑战。本文采用简单的两步固相法合成了名义成分为Na3+2xZr2‒xMgxSi2PO12 的钠(Na)超离子导体(NASICON)型固体电解质,其中在25 ℃时Na3.3Zr1.85Mg0.15Si2PO12(x=0.15, NZSP-Mg0.15)表现出了3.54 mS∙cm‒1的最高离子电导率。通过深入研究,本文证实晶界成分在决定NASICON总离子电导率中起着至关重要的作用。此外,由于文献中缺乏关于NASICON是否能够提供足够的阳极电化学稳定性来实现高压固态钠电池的研究,我们首先使用了高压Na3(VOPO4)2F (NVOPF)正极来验证其与优化后的NZSP-Mg0.15固体电解质之间的兼容性。通过比较不同配置(低压阴极与高压阴极、液态电解质与固体电解质)电池的电化学性能,以及对循环后的NZSP-Mg0.15进行X射线光电子能谱(XPS)评估,结果表明,NASICON固体电解质在高电压下不够稳定,这证明了研究NASICON固体电解质和高压阴极之间界面的重要性。此外,通过将NZSP-Mg0.15 NASICON 粉末涂在聚乙烯(PE)隔膜(PE@NASICON)上,形成了2.42 A∙h 的碳|PE@NASICON|NaNi2/9Cu1/9Fe1/3Mn1/3O2 非水系钠离子电池,其具有出色的循环性能,在2000 周循环后容量保持率为88%,从而证明涂有NASICON型固体电解质的隔膜具有高可靠性。
《能源前沿(英文)》 doi: 10.1007/s11708-023-0901-9
关键词: interconnector coating plasma spray electrochemical performance Cr diffusion inhibition solid oxide cells (SOCs)
Minimal residual disease in solid tumors: an overview
《医学前沿(英文)》 2023年 第17卷 第4期 页码 649-674 doi: 10.1007/s11684-023-1018-6
关键词: MRD solid tumor CTC ctDNA
Technological development and engineering applications of novel steel-concrete composite structures
Jianguo NIE, Jiaji WANG, Shuangke GOU, Yaoyu ZHU, Jiansheng FAN
《结构与土木工程前沿(英文)》 2019年 第13卷 第1期 页码 1-14 doi: 10.1007/s11709-019-0514-x
In view of China’s development trend of green building and building industrialization, based on the emerging requirements of the structural engineering community, the development and proposition of novel resource-saving high-performance steel-concrete composite structural systems with adequate safety and durability has become a kernel development trend in structural engineering. This paper provides a state of the art review of China’s cutting-edge research and technologies in steel-concrete composite structures in recent years, including the building engineering, the bridge engineering and the special engineering. This paper summarizes the technical principles and applications of the long-span bi-directional composite structures, the long-span composite transfer structures, the comprehensive crack control technique based on uplift-restricted and slip-permitted (URSP) connectors, the steel plate concrete composite (SPCC) strengthen technique, and the innovative composite joints. By improving and revising traditional structure types, the comprehensive superiority of steel-concrete composite structures is well elicited. The research results also indicate that the high-performance steel-concrete composite structures have a promising popularizing prospect in the future.
关键词: high-performance composite structure bi-directional composite composite transfer uplift-restricted and slip-permitted connectors steel plate concrete composite strengthen
High-solid anaerobic digestion of sewage sludge: achievements and perspectives
《环境科学与工程前沿(英文)》 2021年 第15卷 第4期 doi: 10.1007/s11783-020-1364-4
• High-solid anaerobic digestion (HS-AD) of sewage sludge (SS) is overviewed.
关键词: High-solid effect Anaerobic fermentation Methane production Biodegradability Sludge treatment
Review of SO42-/MxOy solid superacid catalysts
Yanni WU, Shijun LIAO
《化学科学与工程前沿(英文)》 2009年 第3卷 第3期 页码 330-343 doi: 10.1007/s11705-009-0208-3
关键词: solid superacid catalyst synthesis method characterization applications
Repercussions of COVID-19 pandemic on solid waste generation and management strategies
《环境科学与工程前沿(英文)》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1407-5
• Implication of COVID-19 on medical waste and MSW generation is studied.
关键词: COVID-19 Medical waste Personal protective equipment Municipal solid waste Waste management
Deep eutectic solvent inclusions for high- composite dielectric elastomers
《化学科学与工程前沿(英文)》 2022年 第16卷 第6期 页码 996-1002 doi: 10.1007/s11705-022-2138-2
关键词: composite materials deep eutectic solvent dielectric elastomer high dielectric constant
《环境科学与工程前沿(英文)》 2022年 第16卷 第8期 doi: 10.1007/s11783-022-1518-7
• Antibiotic azithromycin employed in graphite electrode for EAB biosensor.
关键词: AZM@GP composite electrode EAB-biosensor Water quality early-warning
标题 作者 时间 类型 操作
Ion conduction path in composite solid electrolytes for lithium metal batteries: from polymer rich to
Zhouyu ZHANG, Hao CHEN, Zhenglin HU, Shoubin ZHOU, Lan ZHANG, Jiayan LUO
期刊论文
A review on the development of electrolytes for lithium-based batteries for low temperature applications
期刊论文
Recent advances toward high voltage, EC-free electrolytes for graphite-based Li-ion battery
Tong Zhang, Elie Paillard
期刊论文
Plasma spray coating on interconnector toward promoted solid oxide fuel cells and solid oxide electrolysis
期刊论文
Technological development and engineering applications of novel steel-concrete composite structures
Jianguo NIE, Jiaji WANG, Shuangke GOU, Yaoyu ZHU, Jiansheng FAN
期刊论文